As others have said, it depends a lot on your level of comfort with installing and configuring the OS. I can only share my own experiences and opinions.
I bought the first model released in Australia, WinXP black 16GB
SSD w/ 1GB RAM. The default XP install performed really badly so I wiped the HDD and installed Ubuntu Hardy, netbook remix and upgraded the RAM to 2GB. I later upgraded Ubuntu to Jaunty and got bored of netbook remix so I now run a regular Linux desktop with an Amiga theme, sweet.
The boot time is approx 20 seconds to the login screen and about 5 seconds from login to desktop.
My Ubuntu uses ext2 file systems and has no swap drive. I tend to have 1GB of free RAM available when running Firefox and OpenOffice. I'm running out of storage atm so an upgrade to a 32GB Runcore is on the cards and I'm anticipating a nice reduction in boot time from that upgrade!
On the mobile Internet access front I run Blueman which allows me to expose my Nokia N95 3G Internet as a network device to Ubuntu. Combined with Network Manager this means that from a cold start I can be on the net within 30 to 40 seconds; startup, login, right-click Blueman icon, connect N95 via bluetooth and the Network Manager auto-connects to the Internet. This is really handy on the train as I don't need to plug my phone into the laptop nor pay for an additional connection or have one of those ugly 3G cards sticking out of the Mini. Blueman is a truly amazing tool.
I use the machine for web browsing and email as well as work related stuff like ssh, RDP, Google Apps. OpenOffice provides me with an MS Office compatible suite so I don't miss Windows much... I do have an 8GB SDHC card which has a Windows XP virtual box and Visual Studio Express on it in case I need to work on C++ and C# projects. Windows XP performance under virtual box and Ubuntu is far in excess of the default XP install I found on the machine when I bought it.
I suspect one can do all of the above with OS X but from my perspective OS X is too much of a learning curve for me (I'm a right clicker) and GNU/Linux is something I know well. Based on my experiences I doubt that Windows XP would give me the smooth experience I'm currently getting. Maybe Windows 7 will come close. I might give it a go when I upgrade the
SSD card.